I found little kits of glass paint, with around 8 tubes in each for around 2 euro in World of Wonder, they're really easy to use and excellent value! They come with a tube of glue, which I've never needed to use, as they stick on perfectly without it. We usually paint onto a mirror first (as it's a flat surface). When the design is dry you just peel it off like a sticker. So you don't need to bother with base coats or anything, hope this helps.
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